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By Norbert Bischof, Harry Gubler

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After ongoing spallation, the oxide scale is not replaced by newly formed chromia and the other alloying elements Ni and Fe are oxidised. Eventually the surface grains flake off leaving a surface covered partially by a thin film of aluminium oxide, as observed after 500 h (Fig. 7b). This aluminium oxide layer cannot protect the bulk alloy from corrosive attack. Nitrogen from the gaseous atmosphere diffused into the alloy matrix leading to aluminium nitride formation. 2. For Alloy 602 at 650 °C and 1000 °C, Grabke [16] and Li [10], respectively, observed aluminium oxide on grain boundaries, as was found in the present work.

3 for Alloy 602. 2) results. Assuming that the onset of aluminium nitride formation is related to the breakdown of the high-temperature resistance of the alloys, their lifetime can be estimated. 4. The long-term behaviour of the alloys correlates with the chromium consumption and the remaining chromium content in the bulk alloy. The time of breakdown of the chromia scale can be defined from the chromium depletion in the bulk alloy. If the chromium concentration drops below a critical value, a stable chromia scale cannot be established.

3a) is well known as characteristic of the corrosion in waste incineration plants. Some of the thermally-sprayed coatings could not withstand the corrosive conditions without displaying evidence of corrosion. The reasons for this relate to the material composition and the parameters used for thermal spraying. Corrosion through the grains is evidence of the insufficient corrosion resistance of the coating material. Corrosion along the grain boundaries with layer-shaped flaking of grains was observed in many cases (Fig.

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A Systems Theory Perspective (Infant Development: Perspectives from German-Speaking Countries) by Norbert Bischof, Harry Gubler

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